Organometallic Tantalum Tris(methimazolyl)borato Complexes: [Ta( η 2 -RC≡CR)Cl 2 {HB(mt) 3 }] (R = Ph, Et; mt = methimazolyl)
Date
2007
Authors
Hill, Anthony
Smith, Matthew
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Publisher
American Chemical Society
Abstract
The reactions of Na[HB(mt)3] (mt = methimazolyl) with [Ta(η2-RC≡CR)Cl3(dme)] (R = Ph, Et) provide the structurally characterized complexes [Ta(η2-RC≡CR)Cl 2{HB(mt)3}], the first examples of organometallic tris( methimazolyl )borato derivatives of gr
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Keywords
Keywords: Chirality; Derivatives; Metal complexes; Molecular orientation; Reaction kinetics; Tantalum compounds; Alkyne orientation; Borato derivatives; Organometallic derivatives; Structurally characterized complexes; Organometallics
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Organometallics
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Journal article
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2037-12-31
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