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Organometallic Tantalum Tris(methimazolyl)borato Complexes: [Ta( η 2 -RC≡CR)Cl 2 {HB(mt) 3 }] (R = Ph, Et; mt = methimazolyl)

Date

Authors

Hill, Anthony

Smith, Matthew

Publisher

American Chemical Society

Abstract

The reactions of Na[HB(mt)3] (mt = methimazolyl) with [Ta(η2-RC≡CR)Cl3(dme)] (R = Ph, Et) provide the structurally characterized complexes [Ta(η2-RC≡CR)Cl 2{HB(mt)3}], the first examples of organometallic tris( methimazolyl )borato derivatives of gr

Keywords

Keywords: Chirality; Derivatives; Metal complexes; Molecular orientation; Reaction kinetics; Tantalum compounds; Alkyne orientation; Borato derivatives; Organometallic derivatives; Structurally characterized complexes; Organometallics

URI

http://hdl.handle.net/1885/31684

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

DOI

10.1021/om700615w

Restricted until

2037-12-31

Downloads

File

Description

01_Hill_Organometallic_Tantalum_2007.pdf (110.47 KB)

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