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Transition metal-alkane σ-complexes with oxygen donor co-ligands

Date

Authors

Young, Rowan

Hill, Anthony

Hillier, Warwick

Ball, Graham Edwin

Publisher

American Chemical Society

Abstract

A new family of long-lived alkane θ-complexes of the type (LOEt)Re(CO)2(alkane) [alkane = cyclopentane, cyclohexane, pentane; LOEt = cyclopentadienyltris(diethylphosphito)cobaltate(III)] has been observed using both IR and NMR spectroscopies and computat

Keywords

Keywords: Co-ligands; Cobaltates; Coordination sphere; DFT method; IR and NMR spectroscopy; Metal oxides; Oxygen donors; Cobalt compounds; Coordination reactions; Metallic compounds; Nuclear magnetic resonance spectroscopy; Oxygen; Rhenium; Rhenium compounds; Trans

URI

http://hdl.handle.net/1885/62259

Collections

ANU Research Publications

Source

Journal of the American Chemical Society

Type

Journal article

DOI

10.1021/ja203470y

Restricted until

2037-12-31

Downloads

File

Description

01_Young_Transition_metal-alkane_2011.pdf (953.96 KB)