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Independent Switching of Cubic Nonlinear Optical Properties in a Ruthenium Alkynyl Cruciform Complex by Employing Protic and Electrochemical Stimuli

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Date

2007

Authors

Dalton, Gulliver
Cifuentes, Marie
Petrie, Simon
Stranger, Robert
Samoc, Marek
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The quadrupolar ruthenium alkynyl cruciform complex is reversibly converted to tetravinylidene complex or tetraruthenium(III) tetracationic complex forms by protonation or oxidation, respectively; linear and nonlinear proto- and electrochromism studies reveal independent switching of NLO properties by the protic and electrochemical stimuli, respectively, aspects of which have been rationalized by theoretical studies.

Description

Keywords

Keywords: alkynyl group; ruthenium; article; complex formation; density functional theory; dispersion; electrochemistry; isomerization; molecular model; nonhuman; nonlinear system; oscillation; oxidation reduction reaction; proton transport; signal processing; stim

Citation

URI

http://hdl.handle.net/1885/34505

Collections

ANU Research Publications

Source

Journal of the American Chemical Society

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/ja074205k

Restricted until

2037-12-31

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