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Towards the Total Synthesis of 3-Hydroxyvibsanin E

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Date

2009

Authors

Schwartz, Brett
Denton, Justin R
Bernhardt, Paul
Davies, Huw ML
Williams, Craig

Journal Title

Journal ISSN

Volume Title

Publisher

Georg Thieme Verlag

Abstract

The synthesis of a silyl-protected derivative of 3-hydroxyvibsanin E has been achieved. The key step is a regio-and stereoselective C-H hydroxylation of an advanced tricyclic intermediate by means of a Rubottom oxidation.

Description

Keywords

Keywords: C-H hydroxylation; Hydroxyvibsanin E; Rubottom oxidation; Stereo-selective; Total synthesis; Hydroxylation; Silanes; Oxidation; 15 o methylcyclovibsanin b; 3 hydroxyvibsanin e; 3 o methylfuranovibsanin a; furanovibsanin a; levo 5 epi vibsanin e; plant ext C-H hydroxylation; Hydroxyvibsanin E; Rubottom oxidation

Citation

URI

http://hdl.handle.net/1885/59633

Collections

ANU Research Publications

Source

Synthesis

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1055/s-0029-1216912

Restricted until

2037-12-31

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