Reactions of benzynenickel(0) complexes with thioalkynes: Preparation and coordination of polydentate thioethers containing a 2,3-naphthylene backbone.
Date
2002
Authors
Edwards, Alison
Willis, Anthony
Wenger, Eric
Journal Title
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Volume Title
Publisher
American Chemical Society
Abstract
Double insertion reactions of the thioalkynes MeC≡CS-p-Tol and (MeC≡CSCH2CH2)2S with benzyne-nickel(O) complexes have been used to prepare the 2,3-di(thioether) naphthalene species 2,3-(p-TolS)2-l,4-Me2C10H4 (4) and the 2,3-naphthotrithiacyclononane 2
Description
Keywords
Keywords: Insertion reactions; Aromatic hydrocarbons; Complexation; Synthesis (chemical); X ray diffraction analysis; Organometallics
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Source
Organometallics
Type
Journal article
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2037-12-31