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The seven-membered nickelacycle [NiBr{ o -CH=C(CF 3 )C 6 H 4 CH 2 PPh 2 -κ 2 C,P }{PPh(CH 2 Ph) 2 }].

Date

Authors

Edwards, Alison

Wenger, Eric

Publisher

Munksgaard International Publishers

Abstract

The crystal and molecular structures of a seven-membered nickel compound were investigated. The structures were obtained as the major regioisomer from insertion of HCCCF3 into the Ni-C bond of the five-membered phosphonickelacycle. H atoms were placed in

Keywords

Keywords: Charge coupled devices; Chemical bonds; Crystallization; Diffractometers; Diffusion; Isomers; Molecular structure; Nickel compounds; Nuclear magnetic resonance; Parameter estimation; Polynomials; Probability density function; Single crystals; Solutions; S

URI

http://hdl.handle.net/1885/72498

Collections

ANU Research Publications

Source

Acta Crystallographica Section C: Crystal Structure Communications

Type

Journal article

DOI

10.1107/S0108270102002883

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