Phosphine-stabilised arsenium salts: Water-stable, labile, coordination complexes.

Date

2002

Authors

Porter, Keith
Willis, Anthony
Zank, Johann
Wild, Stanley (Bruce)

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

A series of air- and water-stable tertiary phosphine-stabilized arsenium salts of the type R3P→AsR2+PF6- has been isolated. In the crystal structures of two chiral triarylphosphine complexes of prochiral methylphenylarsenium hexafluorophosphate, the ste

Description

Keywords

Keywords: 2 (methoxymethylphenyl)diphenylphosphine; arsenic derivative; arsine derivative; carbon; methylphenylarsenium hexafluorophosphate; oxygen; phenyl group; phosphine; phosphorus; unclassified drug; water; air; article; atom; chemical bond; chirality; complex

Citation

Source

Inorganic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/ic020410j

Restricted until

2037-12-31