New binding modes for CSe: coinage metal coordination to a tungsten selenocarbonyl complex

Simple item page
dc.contributor.authorFrogley, Benjamin
dc.contributor.authorHill, Anthony
dc.contributor.authorWatson, Lachlan
dc.date.accessioned2020-07-07T01:35:10Z
dc.date.issued2019-07-25
dc.date.updated2020-06-23T00:54:15Z
dc.description.abstractThe new tungsten selenocarbonylate [NEt4][W(uCSe)(CO)2(Tp*)] (Tp* = hydrotris(dimethylpyrazolyl) borate) reacts with group 11 reagents to provide σ–π or isoselenocarbonyl complexes of the form [WM(μ-CSe)(CO)2(PR3)n(Tp*)] (M = Cu, Ag, Au; R = Ph, Cy; n = 1,3) depending on the phosphine stoichiometry or steric bulk. With [Cu(NCMe)4]PF6 and 1,4,7-trithiacyclononane ([9]aneS3) however, the tetrametallic species [WCu3(μ-CSe)(CO)2([9]aneS3)3(Tp*)](PF6)2 is obtained in which one Cu coordinates to the WuC triple bond and two coordinate to the Se atomen_AU
dc.description.sponsorshipWe gratefully acknowledge the Australian Research Council (DP170102695 and DP190100723) for funding.en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.citationDalton Trans., 2019, 48, 12598en_AU
dc.identifier.issn1477-9226en_AU
dc.identifier.urihttp://hdl.handle.net/1885/205873
dc.language.isoen_AUen_AU
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/18010..."The Accepted Version can be archived in a Non-Commercial Repository. 12 months embargo" from SHERPA/RoMEO site (as at 14/12/2020).
dc.publisherRoyal Society of Chemistryen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP170102695en_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP190100723en_AU
dc.rights© 2019 The Royal Society of Chemistryen_AU
dc.sourceDalton Transactionsen_AU
dc.titleNew binding modes for CSe: coinage metal coordination to a tungsten selenocarbonyl complexen_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Access
dcterms.dateAccepted2019-07-23
local.bibliographicCitation.issue33en_AU
local.bibliographicCitation.lastpage12606en_AU
local.bibliographicCitation.startpage12598en_AU
local.contributor.affiliationFrogley, Benjamin, College of Science, ANUen_AU
local.contributor.affiliationHill, Anthony, College of Science, ANUen_AU
local.contributor.affiliationWatson, Lachlan, College of Science, ANUen_AU
local.contributor.authoremailu1045400@anu.edu.auen_AU
local.contributor.authoruidFrogley, Benjamin, u1045400en_AU
local.contributor.authoruidHill, Anthony, u4030185en_AU
local.contributor.authoruidWatson, Lachlan, u5643251en_AU
local.description.notesImported from ARIESen_AU
local.identifier.absfor030204 - Main Group Metal Chemistryen_AU
local.identifier.absfor039904 - Organometallic Chemistryen_AU
local.identifier.absfor030207 - Transition Metal Chemistryen_AU
local.identifier.absseo970102 - Expanding Knowledge in the Physical Sciencesen_AU
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciencesen_AU
local.identifier.ariespublicationu3102795xPUB4520en_AU
local.identifier.citationvolume48en_AU
local.identifier.doi10.1039/c9dt02958cen_AU
local.identifier.thomsonIDWOS:000481917100020
local.identifier.uidSubmittedByu3102795en_AU
local.publisher.urlhttps://pubs.rsc.org/en_AU
local.type.statusAccepted Versionen_AU

Downloads

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
10.1039_c9dt02958c.pdf
Size:
3.37 MB
Format:
Adobe Portable Document Format
Download

Collections

ANU Research Publications

DSpace software copyright © 2002-2024 LYRASIS