Dodecanuclear-Ellipse and Decanuclear-Wheel Nickel(II) Thiolato Clusters with Efficient Femtosecond Nonlinear Absorption

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dc.contributor.authorZhang, Chi
dc.contributor.authorMatsumoto, Tsuyosh
dc.contributor.authorSamoc, Marek
dc.contributor.authorPetrie, Simon
dc.contributor.authorMeng, Suci
dc.contributor.authorCorkery, Timothy
dc.contributor.authorStranger, Robert
dc.contributor.authorZhang, Jinfang
dc.contributor.authorTatsumi, Kazuyuki
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-10T22:54:52Z
dc.date.issued2010
dc.date.updated2016-02-24T10:43:55Z
dc.description.abstract(Figure Presented) Crowned with success: Stepwise coordination of two kinds of thiolate ligands to a nickel (II) center affords a dodecanuclear ellipse (see structure) and two decanuclear wheel-like NiII-thiolato clusters. The wavelength-dependent nonlinear optical behavior of these tiara-like compounds was investigated and supported by theoretical studies. The results suggest that Ni-S π bonds play a crucial role.
dc.identifier.issn1433-7851
dc.identifier.urihttp://hdl.handle.net/1885/59837
dc.publisherWiley-VCH Verlag GMBH
dc.sourceAngewandte Chemie International Edition
dc.subjectKeywords: Cluster compounds; Decanuclear; DFT calculation; Femtoseconds; Nonlinear absorptions; Nonlinear optical behavior; Theoretical study; Thiolate ligands; Ligands; Nickel alloys; Nickel compounds; Optical materials; Wheels; Nonlinear optics; nickel; thiol der Cluster compounds; Nonlinear optics; Td-dft calculations; Thiolate ligands; Tiara structures
dc.titleDodecanuclear-Ellipse and Decanuclear-Wheel Nickel(II) Thiolato Clusters with Efficient Femtosecond Nonlinear Absorption
dc.typeJournal article
local.bibliographicCitation.issue25
local.bibliographicCitation.lastpage4212
local.bibliographicCitation.startpage4209
local.contributor.affiliationZhang, Chi, Jiangsu University
local.contributor.affiliationMatsumoto, Tsuyosh, Nagoya University
local.contributor.affiliationSamoc, Marek, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationPetrie, Simon, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationMeng, Suci, Jiangsu University
local.contributor.affiliationCorkery, Timothy, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationStranger, Robert, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationZhang, Jinfang, Jiangsu University
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationTatsumi, Kazuyuki, Nagoya University
local.contributor.authoruidSamoc, Marek, u9115357
local.contributor.authoruidPetrie, Simon, u9800071
local.contributor.authoruidCorkery, Timothy, u4261121
local.contributor.authoruidStranger, Robert, u8708796
local.contributor.authoruidHumphrey, Mark, u9400918
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.absfor030701 - Quantum Chemistry
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationu4217927xPUB510
local.identifier.citationvolume49
local.identifier.doi10.1002/anie.200907074
local.identifier.scopusID2-s2.0-77953489542
local.identifier.thomsonID000278843400006
local.type.statusPublished Version

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