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Diphenylamino-substituted tristyryl vs. triphenyl isocyanurates: improved conjugation has minimal impact on two-photon absorption

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Triadon, Amedee
Ngo Ndimba, Alphonsine
Richy, Nicolas
Amar, Anissa
Boucekkine, Abdou
Roisnel, Thierry
Cifuentes, Marie
Humphrey, Mark
Blanchard-Desce, Mireille
Mongin, Olivier

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Royal Society of Chemistry

Abstract

This contribution reports the synthesis of C87H60N6O3 (3-NPh2), the tristyryl analogue of the triphenylisocyanurate C81H54N6O3 (2-NPh2) which was previously demonstrated to be an active two-photon absorber. Contrary to expectation, planarization and extension of the central π-system does not lead to a marked improvement of the two-photon absorption cross-section.

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New Journal of Chemistry

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Open Access

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