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Selective adsorption of nitro-substituted aromatics and accelerated hydrolysis of 4-nitrophenyl acetate on carbon surfaces

dc.contributor.authorMeyer, Adam G
dc.contributor.authorDai, Liming
dc.contributor.authorChen, Quidao
dc.contributor.authorEaston, Christopher
dc.contributor.authorXia, Ling
dc.date.accessioned2015-12-13T23:20:31Z
dc.date.available2015-12-13T23:20:31Z
dc.date.issued2001
dc.date.updated2015-12-12T09:03:27Z
dc.description.abstractNitrobenzene, 4-nitrotoluene and 4-nitrophenyl acetate are selectively adsorbed from aqueous 1% sodium dodecyl sulfate solutions onto aligned, randomly oriented and oxidised carbon nanotubes, as well as graphite and C60 fullerene. The rate of hydrolysis of 4-nitrophenyl acetate to 4-nitrophenolate is modestly accelerated through this process. Selective adsorption requires the presence of the surfactant and the hydrolysis of pNPA is accelerated only by a carbon surface that is graphitic in nature.
dc.identifier.issn1144-0546
dc.identifier.urihttp://hdl.handle.net/1885/90744
dc.publisherRoyal Society of Chemistry
dc.sourceNew Journal of Chemistry
dc.subjectKeywords: 4 nitrophenylacetic acid; 4 nitrotoluene; carbon; dodecyl sulfate sodium; fullerene; graphite; nitrobenzene; surfactant; unclassified drug; absorption; aqueous solution; article; chemical reaction; hydrolysis; priority journal; reaction analysis
dc.titleSelective adsorption of nitro-substituted aromatics and accelerated hydrolysis of 4-nitrophenyl acetate on carbon surfaces
dc.typeJournal article
local.bibliographicCitation.issue7
local.bibliographicCitation.lastpage889
local.bibliographicCitation.startpage887
local.contributor.affiliationMeyer, Adam G, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationDai, Liming, CSIRO Molecular Science
local.contributor.affiliationChen, Quidao, CSIRO Molecular Science
local.contributor.affiliationEaston, Christopher, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationXia, Ling, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidMeyer, Adam G, u9612730
local.contributor.authoruidEaston, Christopher, u9500570
local.contributor.authoruidXia, Ling, u9601790
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030606 - Structural Chemistry and Spectroscopy
local.identifier.ariespublicationMigratedxPub21185
local.identifier.citationvolume25
local.identifier.doi10.1039/b101963p
local.identifier.scopusID2-s2.0-0034926044
local.type.statusPublished Version

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