Experimental and computational studies into an ATPH-promoted exo -Selective IMDA reaction: A short total synthesis of Δ 9 -THC
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Pearson, Emma
Kanizaj, Nicholas
Willis, Anthony
Paddon-Row, Michael
Sherburn, Michael
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Wiley-VCH Verlag GMBH
Abstract
(Figure Presented) Reversal of fortune: The inherent cis stereoselectivity of an intramolecular Diels-Alder reaction is reversed through promotion with aluminum tris(2,6-diphenylphenoxide) (ATPH), allowing a total synthesis of the natural product Δ 9-tet
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Chemistry, A European Journal
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2037-12-31