Trends in back-bonding in the series trans-[M(C�CR)Cl(PH3)4] (M = Fe, Ru, Os; R = H, Ph, C6H4NO2-4)
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Delfs, Christopher
Stranger, Robert
McDonagh, Andrew
Humphrey, Mark
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Elsevier
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The electronic structure of the complexes trans-[M(C≡CR)Cl(PH3)4] (M = Fe, Ru, Os; R = H, Ph, C6H4NO2-4) has been investigated using approximate density functional theory in order to examine the M-C back-bonding interaction. For all three metal systems,
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Journal of Organometallic Chemistry
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2037-12-31
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