Resolution and improved synthesis of (±)-arsenicin A: a natural adamantane-type tetraarsenical possessing strong anti-acute promelocytic leukemia cell line activity

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dc.contributor.authorLu, Di
dc.contributor.authorCoote, Michelle
dc.contributor.authorHo, Junming
dc.contributor.authorKilah, Nathan
dc.contributor.authorLin, Ching-Yeh
dc.contributor.authorSalem, Geoffrey
dc.contributor.authorWeir, Michelle
dc.contributor.authorWillis, Anthony
dc.contributor.authorWild, Stanley (Bruce)
dc.contributor.authorDilda, Pierre J
dc.date.accessioned2015-12-07T22:23:51Z
dc.date.issued2012
dc.date.updated2016-02-24T11:34:01Z
dc.description.abstractThe resolution and improved synthesis of the naturally occurring, adamantane-type, tetraarsenical (±)-Arsenicin A is reported. The five-step synthesis of (±)-Arsenicin A from methylenebis(phenylarsinic acid) affords (±)-Arsenicin A as air-stable, color
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/20898
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Air-stable; Asymmetric unit; Chiralpak IA; Colorless crystals; Enantiomeric purity; Glioblastomas; Gold standards; High-level ab initio calculations; Inorganic oxides; Inversion center; Leukemia cells; Methylene groups; Naturally occurring; Oxygen atom; P
dc.titleResolution and improved synthesis of (±)-arsenicin A: a natural adamantane-type tetraarsenical possessing strong anti-acute promelocytic leukemia cell line activity
dc.typeJournal article
local.bibliographicCitation.issue5
local.bibliographicCitation.lastpage1816
local.bibliographicCitation.startpage1808
local.contributor.affiliationLu, Di, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCoote, Michelle, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHo, Junming, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationKilah, Nathan, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationLin, Ching-Yeh, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSalem, Geoffrey, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWeir, Michelle, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWild, Stanley (Bruce), College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationDilda, Pierre J, University of New South Wales
local.contributor.authoremailu4031074@anu.edu.au
local.contributor.authoruidLu, Di, u4219200
local.contributor.authoruidCoote, Michelle, u4031074
local.contributor.authoruidHo, Junming, u4041618
local.contributor.authoruidKilah, Nathan, u4101782
local.contributor.authoruidLin, Ching-Yeh, u4169280
local.contributor.authoruidSalem, Geoffrey, u8505430
local.contributor.authoruidWeir, Michelle, u3360017
local.contributor.authoruidWillis, Anthony, u8512028
local.contributor.authoruidWild, Stanley (Bruce), u7901996
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030204 - Main Group Metal Chemistry
local.identifier.absfor030201 - Bioinorganic Chemistry
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationu5072968xPUB14
local.identifier.citationvolume31
local.identifier.doi10.1021/om201180d
local.identifier.scopusID2-s2.0-84863296675
local.identifier.thomsonID000301331200028
local.identifier.uidSubmittedByu5072968
local.type.statusPublished Version

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