Consistent Experimental and Theoretical Evidence for Long-Lived Intermediate Radicals in Living Free Radical Polymerization
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Feldermann, Achim
Coote, Michelle
Stenzel, Martina H
Davis, Thomas P
Barner-Kowollik, Christopher
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American Chemical Society
Abstract
The cumyl dithiobenzoate (CDB)-mediated reversible addition fragmentation chain transfer (RAFT) polymerization of styrene at 30°C is studied via both kinetic experiments and high-level ab initio molecular orbital calculations. The kinetic data clearly in
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Journal of the American Chemical Society
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2037-12-31