Stacking fault disorder and its diffraction consequences in Ba 3 MNb 2 O 9 (M = Co and Mn) 1:2 triple perovskites

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Liu, Yun
Withers, Raymond
Ting, Valeska
Fitz Gerald, John
Noren, Lasse

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Elsevier

Abstract

This paper considers stacking fault disorder in Ba3M1Nb2O9 (M=Mn2+ or Co2+) 1:2 triple perovskites and how best to model it when refining neutron powder diffraction data. The true local structures of both samples were successfully refined using a coherent stacking fault disordered model. The stacking fault disorder in Ba3MnNb2O9 and Ba3CoNb2O9 affects their dielectric properties.

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Physica B

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2037-12-31