Gold- and Silver-Catalysed Cyclisation Reactions of beta-Amino Allenes

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dc.contributor.authorJoyce, Liam M
dc.contributor.authorWillis, Anthony
dc.contributor.authorHyland, Christopher J T
dc.contributor.authorPyne, Stephen G
dc.date.accessioned2019-06-24T07:05:24Z
dc.date.issued2018
dc.date.updated2019-03-24T07:20:12Z
dc.description.abstractHerein we report the formation of pyrrolines and tetrahydropyridines from the cyclisation reactions of beta-amino allenes by both Au-I and Ag-I catalysts in yields ranging from 5 to 70%. Au-I catalysts favour a 5-endo-dig cyclisation before rapid rearrangement to the 5-exo-dig product, while Ag-I favours a 6-endo-trig cyclisation. We also report the first known Ag2O catalysed cyclisation reaction of an allene which occurred in good yield (61 %).en_AU
dc.description.sponsorshipThe authors thank the University of Wollongong and the Australian Research Council (grant number DP180101332) for the generous funding for this researchen_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn0004-9425en_AU
dc.identifier.urihttp://hdl.handle.net/1885/164192
dc.language.isoen_AUen_AU
dc.publisherCSIRO Publishingen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP180101332en_AU
dc.rights© CSIRO 2018en_AU
dc.sourceAustralian Journal of Chemistryen_AU
dc.titleGold- and Silver-Catalysed Cyclisation Reactions of beta-Amino Allenesen_AU
dc.typeJournal articleen_AU
local.bibliographicCitation.issue9en_AU
local.bibliographicCitation.lastpage689en_AU
local.bibliographicCitation.startpage682en_AU
local.contributor.affiliationJoyce, Liam M, University of Wollongongen_AU
local.contributor.affiliationWillis, Anthony, College of Science, ANUen_AU
local.contributor.affiliationHyland, Christopher J T, University of Wollongongen_AU
local.contributor.affiliationPyne, Stephen G, University of Wollongongen_AU
local.contributor.authoruidWillis, Anthony, u8512028en_AU
local.description.embargo2037-12-31
local.description.notesImported from ARIESen_AU
local.identifier.absfor030606 - Structural Chemistry and Spectroscopyen_AU
local.identifier.absfor030503 - Organic Chemical Synthesisen_AU
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciencesen_AU
local.identifier.ariespublicationu4485658xPUB2362en_AU
local.identifier.citationvolume71en_AU
local.identifier.doi10.1071/CH18197en_AU
local.identifier.thomsonID000445525200007
local.publisher.urlhttp://www.publish.csiro.au/en_AU
local.type.statusPublished Versionen_AU

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