Organometallic Complexes for Nonlinear Optics. 33. Electrochemical Switching of the Third-order Nonlinearity Observed by Simultaneous Femtosecond Degenerate Four-wave Mixing and Pump-probe Measurements
Date
2003
Authors
Powell, Clem
Cifuentes, Marie
Morrall, Joseph
Samoc, Marek
Luther-Davies, Barry
Humphrey, Mark
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American Chemical Society
Abstract
The molecular inorganic compound 1,3,5-{trans-[RuCl(dppe) 2]C≡C-4-C6H4C≡C}3C 6H3 (1) is reversibly oxidized in solution using an optically transparent thin-layer electrochemical (OTTLE) cell, the oxidation to 13+ resulting in the appearance of a stron
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Keywords: Electrochemistry; Electrochromism; Four wave mixing; Inorganic compounds; Molecular structure; Neodymium lasers; Nonlinear optics; Oxidation; Polarization; Hyperpolarizability; Photoisomerization; Transient absorption (TA); Organometallics
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Journal of Physical Chemistry A
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Journal article
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2037-12-31
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