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Triphenylamine Derivatives with Para-Disposed Pendant Electron-Rich Organoiron Alkynyl Substituents: Defining the Magnetic Interactions in a Trinuclear Iron(III) Trication

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Date

2012

Authors

Grelaud, Guillaume
Cador, Olivier
Roisnel, Thierry
Argouarch, Gilles
Cifuentes, Marie
Paul, Frederic
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The syntheses of two triarylamine derivatives featuring one and three electron-rich Fe(II) "(η 2-dppe)(η 5-C 5Me 5)FeC≡C-" pendant substituents in para position(s) on the aryl rings (1, 2) is reported, along with those of their corresponding radical t

Description

Keywords

Keywords: Alkynyls; Antiferromagnetic coupling constant; Aryl rings; Electron-rich; Magnetic interactions; Monocations; Para position; Spin state; Triarylamines; Triphenylamine derivatives; Iron compounds; Organometallics; Synthetic metals

Citation

URI

http://hdl.handle.net/1885/19753

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/om2006358

Restricted until

2037-12-31

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01_Grelaud_Triphenylamine_Derivatives_2012.pdf (411.72 KB)

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