On the unprecedented level of dinitrogen activation in the calix[4]arene complex of Nb(III)
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Terrett, Richard
Cavigliasso, German
Stranger, Robert
Yates, Brian F
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Royal Society of Chemistry
Abstract
The calix[4]arene niobium(iii) complex ([L]Nb-NN-Nb[L] where [L] = p-tert-butylcalix[4]arene), reported to bind N2 in a μ2-linear dimeric capacity and to activate the N2 triple bond to 1.39 Å, corresponding to the longest N2 bond known in the end-on coo
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Dalton Transactions
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2037-12-31