Alkynyl selenolate complexes of iron, nickel, and molybdenum.
Date
2010
Authors
Caldwell, Lorraine
Hill, Anthony
Hulkes, Alexander
McQueen, Caitlin
White, Andrew J P
Williams, David
Journal Title
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Volume Title
Publisher
American Chemical Society
Abstract
The successive treatment of terminal alkynes, HC≡CR (R = C6H4Me-4, SiMe3), withnBuLi and gray selenium affords LiSeC≡CR, which in turn reacts with [FeCl(CO)2(η-C5H5)], [NiCl(PPh3)(η- C5H5)], and [MoI(CO)3(η-C5H5)] to afford the alkynylselenolato co
Description
Keywords
Keywords: Alkynyls; Electrophiles; Low-yield; Terminal alkyne; Acetylene; Iron compounds; Molybdenum; Molybdenum compounds; Selenium; Chromium compounds
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Source
Organometallics
Type
Journal article
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Restricted until
2037-12-31