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Self-assembly of square-planar halide complexes of phosphine-stabilised stibenium salts

Date

Authors

Wielandt, Wolfram

Kilah, Nathan

Willis, Anthony

Wild, Stanley (Bruce)

Publisher

Royal Society of Chemistry

Abstract

Chloride and bromide ions direct the self-assembly of supramolecular square-planar halide complexes in which four trimethylphosphine-stabilised diphenylstibenium ions surround the central halide ion in discrete centrosymmetrical structures of C4h symmetry.

Keywords

Keywords: antimony; bromide; chloride; chlorine; halide; inorganic salt; phosphine; article; chemical interaction; chemical structure; electron; geometry; hydrogen bond; stereochemistry; supramolecular chemistry; X ray crystallography; Antimony; Bromides; Chlorides

URI

http://hdl.handle.net/1885/92801

Collections

ANU Research Publications

Source

Chemical Communications

Type

Journal article

DOI

10.1039/b607136h

Restricted until

2037-12-31

Downloads

File

Description

01_Wielandt_Self-assembly_of_square-planar_2006.pdf (252.82 KB)