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Adiabatic capture theory applied to N+NH ➔ N2+H at low temperature

Date

Authors

Frankcombe, Terry

Nyman, Gunnar

Publisher

American Chemical Society

Abstract

The adiabatic capture centrifugal sudden approximation (ACCSA) has been applied to the ground state reaction N + NH → N2 + H over the temperature range 2-300 K using an existent potential energy surface. The resultant thermal rate constants are in agree

Keywords

Keywords: Centrifugation; Ground state; Potential energy surfaces; Temperature measurement; Thermodynamic stability; Adiabatic capture centrifugal sudden approximation; Adiabatic capture theory; Classical trajectory calculations; Initial rotational state; Thermal r

URI

http://hdl.handle.net/1885/56647

Collections

ANU Research Publications

Source

Journal of Physical Chemistry A

Type

Journal article

DOI

10.1021/jp076422d

Restricted until

2037-12-31

Downloads

File

Description

01_Frankcombe_Adiabatic_capture_theory_2007.pdf (139.74 KB)

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