The fluctuation theorem and dissipation theorem for Poiseuille flow

Abstract

The fluctuation theorem and the dissipation theorem provide relationships to describe nonequilibrium systems arbitrarily far from, or close to equilibrium. They both rely on definition of a central property, the dissipation function. In this manuscript we apply these theorems to examine a boundary thermostatted system undergoing Poiseuille flow. The relationships are verified computationally and show that the dissipation theorem is potentially useful for study of boundary thermostatted systems consisting of complex molecules undergoing flow in the nonlinear regime.