Synthesis, structure, and reactions of binuclear gold(I) complexes containing two different bridging ligands

Date

2001

Authors

Bhargava, Suresh Kumar
Mohr, Fabian
Bennett, Martin
Welling, Lee
Willis, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The binuclear cycloaurated compounds [Au2(μ-C6H3-2-PPh2-n-Me) 2] (n = 5, 1a; n = 6, 1b) react with the digold-(I) complexes [Au2(μ-S2CNnBu2)2] and [Au2(μ-dppm)2](PF6)2 to give heterobridged dinuclear complexes [Au2- (μ-C6H3-2-PPh2-n-Me)(μ-S2 CNnBu2 (

Description

Keywords

Keywords: carbon; dithiocarbamic acid; gold derivative; halogen; iodide; ligand; metal complex; article; atom; complex formation; crystal structure; dimerization; ligand binding; metal binding; oxidation; solid; structure analysis; synthesis

Citation

Source

Inorganic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

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2037-12-31