Synthesis, structure, and reactions of binuclear gold(I) complexes containing two different bridging ligands

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Bhargava, Suresh Kumar
Mohr, Fabian
Bennett, Martin
Welling, Lee
Willis, Anthony

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American Chemical Society

Abstract

The binuclear cycloaurated compounds [Au2(μ-C6H3-2-PPh2-n-Me) 2] (n = 5, 1a; n = 6, 1b) react with the digold-(I) complexes [Au2(μ-S2CNnBu2)2] and [Au2(μ-dppm)2](PF6)2 to give heterobridged dinuclear complexes [Au2- (μ-C6H3-2-PPh2-n-Me)(μ-S2 CNnBu2 (

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Inorganic Chemistry

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Restricted until

2037-12-31