Characterization of novel vanadium(III)/acetate clusters formed in aqueous solution
Date
2005
Authors
Fry, Fiona
Dougan, Brenda
McCann, Nichola
Zeigler, Christopher
Brasch, Nicola
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Publisher
American Chemical Society
Abstract
We report the first structures of simple acetate complexes of vanadium(III) formed in aqueous solution. Paramagnetic 1H NMR spectroscopy titration experiments indicate the formation of two major V(III)/acetate complexes in acidic aqueous solution for acetate/V(III) ≤4, pD 3.50. A novel tetranuclear cluster and a trinuclear cluster have been characterized by X-ray diffraction studies. Mass spectrometry measurements show these clusters retain their integrity in solution.
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Keywords
Keywords: acetic acid derivative; organometallic compound; vanadium; water; article; chemical structure; chemistry; solution and solubility; X ray crystallography; Acetates; Crystallography, X-Ray; Models, Molecular; Organometallic Compounds; Solutions; Vanadium; W
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Source
Inorganic Chemistry
Type
Journal article
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2037-12-31
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