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An Ab Initio Guide to Structure-Reactivity Trends in Reversible Addition Fragmentation Chain Transfer Polymerization

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Krenske, Elizabeth
Izgorodina, Ekaterina
Coote, Michelle

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American Chemical Society

Abstract

The effects of substituents on the addition-fragmentation reaction, P n· + S=C(Z)SR → PnSC·(Z)SR → PnSC(Z)=S + R·, of the reversible addition fragmentation chain transfer (RAFT) process have been studied via high-level ab initio calculations. A num

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Book Title

Controlled/Living Radical Polymerization: From Synthesis to Materials (ACS Symposium Series 944)

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2037-12-31