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Remarkable homology in the electronic spectra of the mixed-valence cation and anion radicals of a conjugated bis(porphyrinyl)butadiyne.

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Date

2002

Authors

Arnold, Dennis
Hartnell, Regan
Heath, Graham
Newby, Leonora
Webster, Richard

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

The p-radical cation and anion of the dizinc complex of a bis(triarylporphyrinyl)butadiyne, 1+ and 1-, respectively, display remarkably similar near-IR signatures, with intense bands near 1000 and 2500 nm, as predicted by the appropriate frontier-orbital model for inter-porphyrin coupling across the conjugated bridge.

Description

Keywords

Keywords: anion; bis(porphyrinyl)butadiyne; cation; porphyrin derivative; radical; unclassified drug; zinc complex; article; chemical structure; conjugation; infrared spectroscopy

Citation

URI

http://hdl.handle.net/1885/72315

Collections

ANU Research Publications

Source

Chemical Communications

Type

Journal article

Book Title

Entity type

Access Statement

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DOI

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