Alkoxy radicals in the gaseous phase: β-scission reactions and formation by radical addition to carbonyl compounds

Rauk, Arvi; Boyd, Russell; Boyd, Susan; Henry, David; Radom, Leo

Alkoxy radicals in the gaseous phase: β-scission reactions and formation by radical addition to carbonyl compounds

Date

2003

Authors

Rauk, Arvi

Boyd, Russell

Boyd, Susan

Henry, David

Radom, Leo

Publisher

NRC Research Press

Abstract

The structures and reactivities of the alkoxy radicals methoxy (CH 3O·), ethoxy (CH3CH2O·), 1-propoxy (CH3CH2CH2O·), 2-propoxy ((CH3)2CHO·), 2-butoxy (CH3CH 2CH(CH3)O·), tert-butoxy ((CH3) 3CO·), prop-2-enoxy (CH2=CHCH2O· ), and but-3-en-2-oxy (CH2