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The Influence of Chiral Auxiliaries and Catalysts on the Selectivity of Intramolecular Conjugate Additions of Pyrrole to N -Tethered Michael Acceptors

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Date

2004

Authors

Banwell, Martin
Beck, Daniel
Smith, Jason A

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

A series of pyrroles incorporating N-tethered acrylates and related groups has been prepared and examined for their capacity to undergo intramolecular Michael addition reactions to form, in a diastereo- or enantio-selective fashion, the corresponding 8-substituted tetrahydroindolizidine or homologues thereof.

Description

Keywords

Keywords: Aldehydes; Catalysts; Hydrogenation; Isomers; Reduction; Stereochemistry; Substrates; Synthesis (chemical); Cyclization; Epoxidation; Michael addition reactions; Addition reactions

Citation

URI

http://hdl.handle.net/1885/78363

Collections

ANU Research Publications

Source

Organic and Biomolecular Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/b312552a

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