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Switching the Cubic Nonlinear Optical Properties of an Electro-, Halo-, and Photochromic Ruthenium Alkynyl Complex Across Six States

Date

2009

Authors

Green, Katy
Cifuentes, Marie
Corkery, Timothy
Samoc, Marek
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

Wiley-VCH Verlag GMBH

Abstract

More than on and off: The title complex (see picture) comprises addressable modules that respond independently to protic (alkynyl ligand⇄vinylidene ligand), electrochemical (metal-centered redox: RuII⇄RuIII), and photochemical (dithienylperfluorocyclo

Description

Keywords

Keywords: Alkynyl complexes; Alkynyl ligands; Cubic nonlinearities; Molecular devices; Non-linear optical properties; Nonlinear absorption; Ring opening; Vinylidene ligands; Absorption; Ligands; Optical materials; Optical properties; Ruthenium; Ruthenium compounds; Alkynyl complexes; Molecular devices; Nonlinear absorption; Nonlinear optics; Organometallics

Citation

Source

Angewandte Chemie International Edition

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1002/anie.200903027

Restricted until

2037-12-31