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Crystallization behaviors of ZnxSb100-x thin films for ultralong data retention phase change memory applications

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Chen, Yimin
Wang, Guoxiang
Shen, Xiang
Xu, Tiefeng
Wang, Rongping
Wu, Liangcai
Lu, Yegang
Li, Junjian
Dai, Shixun
Nie, Qiuhua

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Royal Society of Chemistry

Abstract

ZnxSb100-x films with low Zn content are crystallized in a single-step process with Sb, while the film (Zn/Sb ratio is about 1:1) exhibits a two-step crystallization process with ZnSb metastable and stable phases. Importantly, ZnSb films have higher crystallization temperature (~257 °C), larger crystalline activation energy (~5.63 eV), better 10 year-data-retention (~201 °C) and lower melting temperature (~500 °C).

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CrystEngComm

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2037-12-31