Reductive etherification of aldehydes photocatalyzed by dicarbonyl pentamethylcyclopentadienyl iron complexes

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Argouarch, Gilles
Grelaud, Guillaume
Roisnel, Thierry
Paul, Frederic
Humphrey, Mark

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Elsevier

Abstract

The reductive etherification of aldehydes can be performed by the reaction with dialkylmethylsilanes in the presence of new iron(II) piano-stool catalysts of general formula Cp*Fe(CO)2Ar (Cp* = η5-C5Me5; Ar = Ph, 4-C6H4OCH3, 4-C6H4CH3, Fc). This transfor

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Tetrahedron Letters

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2037-12-31