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Synthesis, reactivity, and some photochemistry of ortho-N,N-dimethylaminomethyl substituted aryl and ferrocenyl pentamethylcyclopentadienyl dicarbonyl iron complexes

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Date

2013

Authors

Grelaud, Guillaume
Roisnel, Thierry
Dorcet, Vincent
Paul, Frederic
Argouarch, Gilles
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

Elsevier

Abstract

Ortho-lithiated N,N-dimethylaminomethyl ferrocene and benzyldimethylamine react with Cp*Fe(CO)2I to give the new complexes ((Cp*Fe(CO)2)-2-(CH2NMe2)C5H 3)Fe(Cp) and Cp*Fe(CO)2-C6H4(o- CH2NMe2). Access to a wide variety of alkoxy-substituted complexes ((Cp

Description

Keywords

Keywords: Alcoholysis; Carbonyl ligand; Chelated complex; Ferrocenes; Ferrocenyl; Iron complex; Pentamethylcyclopentadienyl; Quaternization; Organometallics; Photolysis; Synthesis (chemical); Iron compounds Alcoholysis; Ferrocenes; Iron complexes; Piano-stool structures

Citation

URI

http://hdl.handle.net/1885/62661

Collections

ANU Research Publications

Source

Journal of Organometallic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1016/j.jorganchem.2013.05.031

Restricted until

2037-12-31

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01_Grelaud_Synthesis,_reactivity,_and_2013.pdf (1.45 MB)

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