Benzyne addition to a metal-carbon multiple bond

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dc.contributor.authorBarnett, Harrison
dc.contributor.authorHill, Anthony
dc.date.accessioned2024-03-14T03:21:12Z
dc.date.issued2021
dc.date.updated2022-11-13T07:16:27Z
dc.description.abstractThe linear mu-carbido complex [Rh-2(mu-C)Cl-2(dppm)(2)] (dppm = bis(diphenylphosphino)methane) reacts with a benzyne equivalent (Me3SiC6H4OTf-2/F-) to afford [Rh-2(mu-CC6H4)(mu-Cl)(C6H5)Cl-2(mu-dppm)(2)], in which the benzyne moiety adds across one of the two metal-carbon double bonds.en_AU
dc.description.sponsorshipWe gratefully acknowledge the Australian Research Council (DP200101222 and DP190100723) for funding.en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn1477-9226en_AU
dc.identifier.urihttp://hdl.handle.net/1885/315994
dc.language.isoen_AUen_AU
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/18010..."The Accepted Version can be archived in a Non-Commercial Institutional Repository. 12 months embargo" from SHERPA/RoMEO site (as at 19/03/2024).
dc.publisherRoyal Society of Chemistryen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP200101222en_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP190100723en_AU
dc.rightsThis journal is © The Royal Society of Chemistry 2021en_AU
dc.sourceDalton Transactionsen_AU
dc.titleBenzyne addition to a metal-carbon multiple bonden_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Access
local.bibliographicCitation.lastpage9387en_AU
local.bibliographicCitation.startpage9383en_AU
local.contributor.affiliationBarnett, Harrison, OTH Other Departments, ANUen_AU
local.contributor.affiliationHill, Anthony, College of Science, ANUen_AU
local.contributor.authoruidBarnett, Harrison, u5370150en_AU
local.contributor.authoruidHill, Anthony, u4030185en_AU
local.description.notesImported from ARIESen_AU
local.identifier.absfor340209 - Organometallic chemistryen_AU
local.identifier.ariespublicationa383154xPUB20759en_AU
local.identifier.citationvolume27en_AU
local.identifier.doi10.1039/d1dt01402aen_AU
local.identifier.thomsonIDWOS:000669571900001
local.publisher.urlhttp://pubs.rsc.org/en/Journals/JournalIssues/DTen_AU
local.type.statusAccepted Versionen_AU

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