Benzyne addition to a metal-carbon multiple bond
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Authors
Barnett, Harrison
Hill, Anthony
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Volume Title
Publisher
Royal Society of Chemistry
Abstract
The linear mu-carbido complex [Rh-2(mu-C)Cl-2(dppm)(2)] (dppm = bis(diphenylphosphino)methane) reacts with a benzyne equivalent (Me3SiC6H4OTf-2/F-) to afford [Rh-2(mu-CC6H4)(mu-Cl)(C6H5)Cl-2(mu-dppm)(2)], in which the benzyne moiety adds across one of the two metal-carbon double bonds.
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Source
Dalton Transactions
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Access Statement
Open Access