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Stannylene or Metallastanna(IV)ocane: A Matter of Formalism

Date

Authors

Brendler, Erica

Wachtler, Erik

Heine, Thomas

Zhechkov, Lyuben

Langer, Thorsten

Pottgen, Rainer

Hill, Anthony

Wagler, Jorg

Publisher

Wiley-VCH Verlag GMBH

Abstract

Pushmi-pullyu with palladium: Although created by Ïa donation from SnCl2 to a PdII complex, the Sn-Pd bonds in the compounds depicted exhibit formal Ïa donation in the opposite direction. Computational and spectroscopic data support stannylpalladium (Pd

Keywords

Keywords: Coordination chemistry; hypercoordination; Spectroscopic data; Stannylenes; transition-metal basicity; Alkalinity; Coordination reactions; Palladium compounds; Tin; Transition metals; Palladium; organometallic compound; palladium; tin; article; chemical s coordination chemistry; hypercoordination; palladium; tin; transition-metal basicity

URI

http://hdl.handle.net/1885/51196

Collections

ANU Research Publications

Source

Angewandte Chemie International Edition

Type

Journal article

DOI

10.1002/anie.201007967

Restricted until

2037-12-31

Downloads

File

Description

01_Brendler_Stannylene_or_2011.pdf (168.15 KB)

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