The Reversible Addition: Fragmentation Chain Transfer Process and the Strength and Limitations of Modeling: Comment on the Magnitude of the Fragmentation Rate Coefficient

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Date

2003

Authors

Barner-Kowollik, Christopher
Coote, Michelle
Davis, Thomas P
Radom, Leo
Vana, Philipp

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Volume Title

Publisher

Wiley-VCH Verlag GMBH

Abstract

There is appreciable uncertainty concerning the magnitude of the fragmentation rate coefficient of the intermediate radical in reversible addition-fragmentation chain transfer (RAFT) polymerizations. A large proportion of the experimental and theoretical

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Keywords

Keywords: Free radicals; Molecular weight; Organic compounds; Temperature; Fragmentation rate coefficient; Living free radical polymerization; Phenyl groups; Quantum chemistry; Reversible addition-fragmentation chain transfer polymerizations; Polymerization; polyme Kinetics (polym.); Living free-radical polymerization; Modeling; Quantum chemistry; Reversible addition-fragmentation chain transfer (RAFT)

Citation

URI

http://hdl.handle.net/1885/88584

Collections

ANU Research Publications

Source

Journal of Polymer Science: Part A: Polymer Chemistry

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Journal article

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DOI

10.1002/pola.10854

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