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Spectroscopic and Catalytic Characterization of a Functional Fe III Fe II Biomimetic for the Active Site of Uteroferrin and Protein Cleavage

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Authors

Smith, Sarah J
Peralta, Rosely A
Jovito, Rafael
Horn, Adolfo
Bortoluzzi, Adailton J
Noble, Christopher J.
Hanson, Graeme
Stranger, Robert
Jayaratne, Vidura
Cavigliasso, German

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American Chemical Society

Abstract

A mixed-valence complex, [FeIIIFeIIL1(μ-OAc)2]BF4·H2O, where the ligand H2L1 = 2-{[[3-[((bis-(pyridin-2-ylmethyl)amino)methyl)-2-hydroxy-5-methylbenzyl] (pyridin-2-ylmethyl)amino]methyl]phenol}, has been studied with a range of techniques, and, where po

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Inorganic Chemistry

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2037-12-31