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Weakly coordinating counter-ions for highly efficient catalysis of intramolecular hydroamination

Date

Authors

Dabb, Serin L.

Ho, Joanne H H

Hodgson, Richard

Messerle, Barbara Ann

Wagler, Jorg

Publisher

Royal Society of Chemistry

Abstract

A series of cationic rhodium(i) and iridium(i) complexes of the type [M(L∩L)(C2)]BArF24 (where M = Rh or Ir, L∩L = bis(pyrazol-1-yl)methane (bpm), bis(N-methylimidazol-2-yl)methane (bim) or 1-(2-(diphenylphosphino)ethyl)-3,5- diphenylpyrazole (Ph2PyP)

Keywords

Keywords: Catalytic activities; Complexes containing; Cyclisation; Cyclooctadiene; Diphenylphosphino; Good yields; Highly efficient; Intramolecular hydroamination; Microwave reactors; Phenylethynyl; Rhodiums (i); Tetrakis; Trifluoro methyls; X-ray crystallographies

URI

http://hdl.handle.net/1885/54589

Collections

ANU Research Publications

Source

Dalton Transactions

Type

Journal article

DOI

10.1039/b814168a

Restricted until

2037-12-31

Downloads

File

Description

01_Dabb_Weakly_coordinating_2009.pdf (218.87 KB)

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