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Di- and zerovalent platinaboratranes: The first pentacoordinate d 10 platinum(0) complex

Date

Authors

Crossley, Ian R

Hill, Anthony

Publisher

American Chemical Society

Abstract

The reaction of [PtCl2(PPh3)2 with Na[H-B(mt)3] (mt = methimazolyl) affords the platinaboratrane salt [PtH(PPh3){B(mt)3}]Cl(PtII→B), the first example of a metallaboratrane with the metal center in the +2 oxidation state. Base-induced dehydrochlorina-ti

Keywords

Keywords: Boron compounds; Chemical relaxation; Computer simulation; Natural frequencies; Nuclear magnetic resonance spectroscopy; Organometallics; Oxidation; Reaction kinetics; Atomic number; Chemical shift; Electroneutrality; Platinum compounds

URI

http://hdl.handle.net/1885/86800

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

DOI

10.1021/om040114

Restricted until

2037-12-31

Downloads

File

Description

01_Crossley_Di-_and_zerovalent_2004.pdf (97.26 KB)