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Heteroleptic Tripalladium(II) Cages

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Authors

Findlay, John
Patil, Komal M
Gardiner, Michael
MacDermott-Opeskin, Hugo
O'Mara, Megan
Kruger, Paul E.
Preston, Dan

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Wiley-VCH Verlag GMBH

Abstract

There is a concerted attempt to develop self-assembled metallo-cages of greater structural complexity, and heteroleptic PdII cages are emerging as prime candidates in these efforts. Most of these are dinuclear: few examples of higher nuclearity have been reported. We demonstrate here a robust method for the formation of tripalladium(II) cages from the 2 : 3 : 3 combination of a tritopic ligand, PdII, and a selection of ditopic ligands of the correct size and geometry.

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Chemistry - An Asian Journal

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Restricted until

2099-12-31