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A Bimetallic Complex Spanned by the C 4 H Ligand: Synthesis of [Cl(CO) 2 L 2 RuC≡CCH=C=RuL 2 (η-C 5 H 5 )PF 6 (L = PPh 3 )

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Date

2005

Authors

Bartlett, Michael
Hill, Anthony
Smith, Matthew

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The synthesis of the first example of a bime-tallic complex spanned by the C4H alkynylvinylidene ligand, [Cl(CO)2L 2RuC≡CCH=C-RuL2(η-C5H 5]PF6 (L = PPh3), is reported: the reaction of [Ru(CO)2L3] with butadiyne provides [RuH(C≡CC≡ CH)(CO)2L2], whic

Description

Keywords

Keywords: Bimetals; Cerium compounds; Derivatives; Molecular structure; Reaction kinetics; Synthesis (chemical); Bimetallic complex; Chloro derivatives; Deprotonation; Complexation

Citation

URI

http://hdl.handle.net/1885/76646

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/om050800o

Restricted until

2037-12-31

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