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Exploiting multiple nucleophilic sites on pyrrole for the assembly of polyheterocyclic frameworks: application to a formal total synthesis of (±)-aspidospermidine

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Date

2002

Authors

Banwell, Martin
Smith, Jason A

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

The tricyclic ketone 19, an advanced intermediate in Aubé's recently reported synthesis of aspidospermidine (4), is prepared in twelve steps from pyrrole (3). The key transformations involve a previously described intramolecular Michael addition reaction

Description

Keywords

Keywords: Addition reactions; Derivatives; Friedel-Crafts reaction; Hydrogenation; Synthesis (chemical); Michael addition reactions; Ketones

Citation

URI

http://hdl.handle.net/1885/72397

Collections

ANU Research Publications

Source

Journal of the Chemical Society, Perkin Transactions 1

Type

Journal article

Book Title

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