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Bi- and tetranuclear tricarbido complexes: μ,σ:σ' and μ,σ:σ':π ⊥ coordination of bridging C 3 ligands

Date

Authors

Dewhurst, Rian

Hill, Anthony

Willis, Anthony

Publisher

American Chemical Society

Abstract

Fluoride-mediated desilylation of the propargylidyne [W(≡CC≡CSiMe3)(CO)2{HB(Pz)3}] (1; pz = pyrazol-1-yl) in the presence of [RhCl(CO)(PPh3)2] provides the bimetallic complex [Rh(C≡C≡W(CO) 2{HB-(pz)3})(CO)(PPh3)2] (2b), which reacts with iodine to

Keywords

Keywords: Carbon; Chromatographic analysis; Organometallics; Oxidation; Resonance; Rhodium; Synthesis (chemical); Desilylation; Dichloromethane solution; Molecular geometry; Trcarbido complexes; Complexation

URI

http://hdl.handle.net/1885/86820

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

DOI

10.1021/om0401152

Restricted until

2037-12-31

Downloads

File

Description

01_Dewhurst_Bi-_and_tetranuclear_2004.pdf (139.45 KB)