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A Bis-Carbyne (Ethanediylidyne) Complex via the Catalytic Demercuration of a Mercury Bis(carbido) Complex

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Date

2009

Authors

Colebatch, Annie
Cordiner, Richard
Hill, Anthony
Nguyen, Thi Kelly
Shang, Rong
Willis, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

Successive treatment of [Mo(≡CBr)(CO)2{HB(pzMe 2)3}] (pz= pyrazol-1-yl) with "BuLi and mercuric chloride provides the bis(carbido)mercuriaÍ complex Hg[C=Mo(CO) 2{HB(pzMe2)3}]2, which is catalytically demercurated by [RhCl(CO)(PPh3)J to provide the bis-

Description

Keywords

Keywords: Carbynes; Catalytic demercuration; CBr; Mercuric chloride; Chlorine compounds; Hysteresis motors; Mercury (metal); Mercury compounds; Molybdenum; Rhodium compounds; Molybdenum compounds

Citation

URI

http://hdl.handle.net/1885/56971

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/om900462p

Restricted until

2037-12-31

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Description
01_Colebatch_A_Bis-Carbyne_2009.pdf (1.68 MB)

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