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Strategic use of amino acid N -substituents to limit α-carbon-centered radical formation and consequent loss of stereochemical integrity

Date

2003

Authors

Croft, Anna
Easton, Christopher
Kociuba, Katherine
Radom, Leo

Journal Title

Journal ISSN

Volume Title

Publisher

Pergamon-Elsevier Ltd

Abstract

Ab initio calculations have been used to investigate the effect of N-substituents on the stability of α-carbon-centered amino acid radicals. Optimized structures of glycine derivatives and related substituted methanes, and the corresponding radicals, wer

Description

Keywords

Keywords: amino acid; carbon; fluorine derivative; glycine derivative; hydrogen; methane; n bromosuccinimide; radical; ab initio calculation; acylation; article; atom; chemical structure; chirality; comparative study; priority journal; radical reaction; reaction an

Citation

Source

Tetrahedron: Asymmetry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1016/S0957-4166(03)00542-1

Restricted until