Total syntheses of the furanosesquiterpenes crassifolone and dihydrocrassifolone via an Au(I)-catalysed intramolecular Michael addition reaction

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dc.contributor.authorMenon, Rajeev
dc.contributor.authorBanwell, Martin
dc.date.accessioned2015-12-10T22:41:18Z
dc.date.issued2010
dc.date.updated2016-02-24T10:23:42Z
dc.description.abstractThe racemic modifications of title natural products 1 and 2 have been synthesised for the first time. The key step was the Au(i)-catalysed conversion of the furanyl-substituted ynone 13 into the annulated furan 14.
dc.identifier.issn1477-0520
dc.identifier.urihttp://hdl.handle.net/1885/57835
dc.publisherRoyal Society of Chemistry
dc.sourceOrganic and Biomolecular Chemistry
dc.subjectKeywords: Dihydrocrassifolone; Furanosesquiterpenes; Intramolecular Michael addition; Natural products; Total synthesis; Addition reactions; Essential oils; Catalysis; benzofuran derivative; gold; sesquiterpene; article; catalysis; chemical structure; chemistry; sy
dc.titleTotal syntheses of the furanosesquiterpenes crassifolone and dihydrocrassifolone via an Au(I)-catalysed intramolecular Michael addition reaction
dc.typeJournal article
local.bibliographicCitation.issue24
local.bibliographicCitation.lastpage5485
local.bibliographicCitation.startpage5483
local.contributor.affiliationMenon, Rajeev, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationBanwell, Martin, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidMenon, Rajeev, u3743174
local.contributor.authoruidBanwell, Martin, u9500594
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationu4005981xPUB417
local.identifier.citationvolume8
local.identifier.doi10.1039/C0OB00487A
local.identifier.scopusID2-s2.0-78649496730
local.identifier.thomsonID000284610600002
local.type.statusPublished Version

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