The structures of three new Galbulimima alkaloids
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Mander, Lewis
Willis, Anthony
Herlt, Anthony
Taylor, Walter C
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Elsevier
Abstract
The structures of three new alkaloids isolated from the bark of the rain forest tree Galbulimima belgraveana, have been determined by a combination of NMR spectroscopy and X-ray crystallography. One of the alkaloids, himgrine (5), was shown to be an oxygenated derivative of himbacine (1), while the second, GB16, (8) proved to be identical with a degradation product from himgaline (4). The remaining alkaloid, GB17 (12) possesses an entirely new and unexpected skeleton.
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Tetrahedron Letters
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2037-12-31
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