Reactivity of cyclooligophosphanes: synthesis and structural characterisation of cyclo -1,4-(BH 3 ) 2 (P 4 Ph 4 CH 2 ) and cyclo -1,2-(BH 3 ) 2 (P 5 Ph 5 )
Date
2006
Authors
Wolf, Robert
Finger, Markus
Limburg, Carolin
Willis, Anthony
Wild, Stanley (Bruce)
Hey-Hawkins, Evamarie
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Royal Society of Chemistry
Abstract
The borane complexes cyclo-1,4-(BH3)2(P 4Ph4CH2) (3) and cyclo-1,2-(BH 3)2(P5Ph5) (4) were prepared by reaction of cyclo-(P4Ph4CH2) and cyclo-(P 5Ph5) with BH3(SMe2). Only the 2: 1 complexes 3 and 4 were isolated, even when an excess of the borane source
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Keywords
Keywords: Boron; Carbon; Hydrogen; Isomers; Mixtures; Nuclear magnetic resonance spectroscopy; Synthesis (chemical); X ray analysis; Borane complexes; Cyclooligophosphanes; Diastereomers; Lithium salt; Stereoisomer; Organic compounds; borane derivative; cation; pho
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Dalton Transactions
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Journal article
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2037-12-31
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